Lewis Base Stabilized Oxophosphonium Ions
Totally OXOme! Monomeric oxophosphonium ions have been prepared from N‐heterocyclic phosphenium ions and triethylamine or pyridine N‐oxides (see picture; Dipp=2,6‐diisopropylphenyl). Their structures were confirmed by single‐crystal X‐ray crystallography.
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Veröffentlicht in: | Angewandte Chemie International Edition 2012-10, Vol.51 (43), p.10836-10840 |
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creator | Hendsbee, Arthur D. Giffin, Nick A. Zhang, Yaoting Pye, Cory C. Masuda, Jason D. |
description | Totally OXOme! Monomeric oxophosphonium ions have been prepared from N‐heterocyclic phosphenium ions and triethylamine or pyridine N‐oxides (see picture; Dipp=2,6‐diisopropylphenyl). Their structures were confirmed by single‐crystal X‐ray crystallography. |
doi_str_mv | 10.1002/anie.201206112 |
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subjects | cations Crystallography Dipping Lewis acids Lewis base main group elements phosphorus phosphorus heterocycles Pictures Pyridines Single crystals Triethylamine X-rays |
title | Lewis Base Stabilized Oxophosphonium Ions |
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