Lewis Base Stabilized Oxophosphonium Ions

Totally OXOme! Monomeric oxophosphonium ions have been prepared from N‐heterocyclic phosphenium ions and triethylamine or pyridine N‐oxides (see picture; Dipp=2,6‐diisopropylphenyl). Their structures were confirmed by single‐crystal X‐ray crystallography.

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Veröffentlicht in:Angewandte Chemie International Edition 2012-10, Vol.51 (43), p.10836-10840
Hauptverfasser: Hendsbee, Arthur D., Giffin, Nick A., Zhang, Yaoting, Pye, Cory C., Masuda, Jason D.
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container_issue 43
container_start_page 10836
container_title Angewandte Chemie International Edition
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creator Hendsbee, Arthur D.
Giffin, Nick A.
Zhang, Yaoting
Pye, Cory C.
Masuda, Jason D.
description Totally OXOme! Monomeric oxophosphonium ions have been prepared from N‐heterocyclic phosphenium ions and triethylamine or pyridine N‐oxides (see picture; Dipp=2,6‐diisopropylphenyl). Their structures were confirmed by single‐crystal X‐ray crystallography.
doi_str_mv 10.1002/anie.201206112
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subjects cations
Crystallography
Dipping
Lewis acids
Lewis base
main group elements
phosphorus
phosphorus heterocycles
Pictures
Pyridines
Single crystals
Triethylamine
X-rays
title Lewis Base Stabilized Oxophosphonium Ions
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