Lewis Base Stabilized Oxophosphonium Ions

Lewis Base Stabilized Oxophosphonium Ions

Totally OXOme! Monomeric oxophosphonium ions have been prepared from N‐heterocyclic phosphenium ions and triethylamine or pyridine N‐oxides (see picture; Dipp=2,6‐diisopropylphenyl). Their structures were confirmed by single‐crystal X‐ray crystallography.

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Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie International Edition 2012-10, Vol.51 (43), p.10836-10840
Hauptverfasser: Hendsbee, Arthur D., Giffin, Nick A., Zhang, Yaoting, Pye, Cory C., Masuda, Jason D.
Format: Artikel
Sprache:eng
Schlagworte:
cations
Crystallography
Dipping
Lewis acids
Lewis base
main group elements
phosphorus
phosphorus heterocycles
Pictures
Pyridines
Single crystals
Triethylamine
X-rays
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Beschreibung
Zusammenfassung:Totally OXOme! Monomeric oxophosphonium ions have been prepared from N‐heterocyclic phosphenium ions and triethylamine or pyridine N‐oxides (see picture; Dipp=2,6‐diisopropylphenyl). Their structures were confirmed by single‐crystal X‐ray crystallography.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201206112