FeCl sub(2)-Promoted Cleavage of the Unactivated C--C Bond of Alkylarenes and Polystyrene: Direct Synthesis of Arylamines

FeCl sub(2)-Promoted Cleavage of the Unactivated C--C Bond of Alkylarenes and Polystyrene: Direct Synthesis of Arylamines

Ironing it out: An efficient and convenient nitrogenation strategy involving C--C bond cleavage for the straightforward synthesis of versatile arylamines is presented. Various alkyl azides and alkylarenes, including the common industrial by-product cumene, react using this protocol. Moreover, this m...

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Veröffentlicht in:Angewandte Chemie International Edition 2012-07, Vol.51 (28), p.6971-6975
Hauptverfasser: Qin, Chong, Shen, Tao, Tang, Conghui, Jiao, Ning
Format: Artikel
Sprache:eng
Schlagworte:
Amines
Bonding
Byproducts
Cleavage
Cumene
Organic compounds
Polystyrene resins
Strategy
Synthesis
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Zusammenfassung:Ironing it out: An efficient and convenient nitrogenation strategy involving C--C bond cleavage for the straightforward synthesis of versatile arylamines is presented. Various alkyl azides and alkylarenes, including the common industrial by-product cumene, react using this protocol. Moreover, this method provides a potential strategy for the degradation of polystyrene.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201202464