Ultraviolet-Ultraviolet Hole Burning Spectroscopy in a Quadrupole Ion Trap: Dibenzo[18]crown-6 Complexes with Alkali Metal Cations

Ultraviolet-Ultraviolet Hole Burning Spectroscopy in a Quadrupole Ion Trap: Dibenzo[18]crown-6 Complexes with Alkali Metal Cations

Conformation selective: A new technique of ultraviolet–ultraviolet hole burning spectroscopy that can be applied to ions stored in a quadrupole ion trap (QIT) is developed and used to obtain the conformation‐selective electronic spectra of dibenzo[18]crown‐6 complexes with alkali metal cations (M+,...

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Veröffentlicht in:Angewandte Chemie International Edition 2012-07, Vol.51 (29), p.7297-7300
Hauptverfasser: Choi, Chang Min, Choi, Dae Ho, Heo, Jiyoung, Kim, Nam Joon, Kim, Seong Keun
Format: Artikel
Sprache:eng
Schlagworte:
Alkali metals
Cations
Cations - chemistry
Coordination Complexes - chemistry
Crown Ethers - chemistry
Electronic spectra
electronic spectroscopy
Equipment Design
gas-phase chemistry
Hole burning
laser spectroscopy
mass spectrometry
Metals, Alkali - chemistry
Pictures
Quadrupoles
Spectroscopy
Spectrum Analysis - instrumentation
Ultraviolet Rays
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Zusammenfassung:Conformation selective: A new technique of ultraviolet–ultraviolet hole burning spectroscopy that can be applied to ions stored in a quadrupole ion trap (QIT) is developed and used to obtain the conformation‐selective electronic spectra of dibenzo[18]crown‐6 complexes with alkali metal cations (M+, see picture; F+=fragment).
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201202640