Local Switching of Chemical Patterns through Light-Triggered Unfolding of Creased Hydrogel Surfaces

Visible light induces switching of surface chemical patterns based on hybrid gels of thermally responsive poly(N‐isopropyl acrylamide) copolymer networks containing iron oxide nanoparticles. The swelling of these hybrid gels is reduced upon illumination (see picture), allowing controlled unfolding o...

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Veröffentlicht in:Angewandte Chemie International Edition 2012-07, Vol.51 (29), p.7146-7149
Hauptverfasser: Yoon, Jinhwan, Bian, Pei, Kim, Jungwook, McCarthy, Thomas J., Hayward, Ryan C.
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Sprache:eng
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Zusammenfassung:Visible light induces switching of surface chemical patterns based on hybrid gels of thermally responsive poly(N‐isopropyl acrylamide) copolymer networks containing iron oxide nanoparticles. The swelling of these hybrid gels is reduced upon illumination (see picture), allowing controlled unfolding of creased features formed owing to an elastic surface instability.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201202692