A Water-Stable Porphyrin-Based Metal-Organic Framework Active for Visible-Light Photocatalysis

A Water-Stable Porphyrin-Based Metal-Organic Framework Active for Visible-Light Photocatalysis

Light‐harvesting MOFs: A new porous porphyrinic metal–organic framework (MOF; see picture) was obtained by hydrothermal synthesis. The chemical and thermal stability of the material allows a postsynthetic insertion of zinc in the center of the porphyrin. The visible‐light photocatalytic activity of...

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Veröffentlicht in:Angewandte Chemie International Edition 2012-07, Vol.51 (30), p.7440-7444
Hauptverfasser: Fateeva, Alexandra, Chater, Philip A., Ireland, Christopher P., Tahir, Asif A., Khimyak, Yaroslav Z., Wiper, Paul V., Darwent, James R., Rosseinsky, Matthew J.
Format: Artikel
Sprache:eng
Schlagworte:
heterogeneous catalysis
Hydrogen evolution
hydrogen production
Insertion
Metal-organic frameworks
Photocatalysis
Pictures
porphyrinoids
Porphyrins
Synthesis
Thermal stability
Zinc
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Zusammenfassung:Light‐harvesting MOFs: A new porous porphyrinic metal–organic framework (MOF; see picture) was obtained by hydrothermal synthesis. The chemical and thermal stability of the material allows a postsynthetic insertion of zinc in the center of the porphyrin. The visible‐light photocatalytic activity of this porphyrin‐based material is shown for the sacrificial hydrogen evolution from water.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201202471