Polymerization of Ethylene through Reversible Addition-Fragmentation Chain Transfer (RAFT)

Polymerization of Ethylene through Reversible Addition-Fragmentation Chain Transfer (RAFT)

The present paper reports the first example of a controlled radical polymerization of ethylene using reversible addition–fragmentation chain transfer (RAFT) in the presence of xanthates (Alkyl‐OC(S)S‐R) as controlling agents under relative mild conditions (70 °C,

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Veröffentlicht in:Angewandte Chemie 2014-06, Vol.126 (26), p.6801-6804
Hauptverfasser: Dommanget, Cédric, D'Agosto, Franck, Monteil, Vincent
Format: Artikel
Sprache:eng ; ger
Schlagworte:
Addition polymerization
Chain transfer
Chemistry
Copolymere
Ethylene
Fragmentation
Polyethylen
Polymerisationen
Polymerization
Radicals
RAFT
Rafts
Reagents
Vinyl acetate
Vinylacetat
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Zusammenfassung:The present paper reports the first example of a controlled radical polymerization of ethylene using reversible addition–fragmentation chain transfer (RAFT) in the presence of xanthates (Alkyl‐OC(S)S‐R) as controlling agents under relative mild conditions (70 °C,
ISSN:0044-8249
1521-3757
DOI:10.1002/ange.201403491