Distillable Ionic Liquids: Reversible Amide OAlkylation

Distillable Ionic Liquids: Reversible Amide OAlkylation

Put it in reverse: The recycling of ionic liquids (ILs) by distillation of the regenerated volatile precursors was demonstrated to be feasible by using low-cost amide-cation-derived aprotic ionic liquids prepared from reversible Oalkylation. The low viscosity (21.6cP at 25°C), high conductivity (15....

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Veröffentlicht in:Angewandte Chemie International Edition 2013-12, Vol.52 (50), p.13392-13396
Hauptverfasser: Chen, Zheng-Jian, Xi, Hong-Wei, Lim, Kok Hwa, Lee, Jong-Min
Format: Artikel
Sprache:eng
Schlagworte:
Amides
Distillation
Ionic liquids
Precursors
Recycling
Viscosity
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Beschreibung
Zusammenfassung:Put it in reverse: The recycling of ionic liquids (ILs) by distillation of the regenerated volatile precursors was demonstrated to be feasible by using low-cost amide-cation-derived aprotic ionic liquids prepared from reversible Oalkylation. The low viscosity (21.6cP at 25°C), high conductivity (15.45mScm(-1) at 25°C), and wide electrochemical windows (ca. 4.5V) of the ILs show potential for electrochemical applications.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201306476