Chemistry at the Nanoscale: Synthesis of an N[at]C sub(60)-N[at]C sub(60) Endohedral Fullerene Dimer

Chemistry at the Nanoscale: Synthesis of an N[at]C sub(60)-N[at]C sub(60) Endohedral Fullerene Dimer

Rattling the cage: The rapid one-pot double 1,3-dipolar cycloaddition reaction of the rare endohedral fullerene N[at]C sub(60) to an oligo(p-phenylene polyethylene) bis(aldehyde) using a novel amino acid derivative as an anchoring group is reported. The method provides the first example of a chemica...

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Veröffentlicht in:Angewandte Chemie International Edition 2012-04, Vol.51 (15), p.3587-3590
Hauptverfasser: Farrington, B J, Jevric, M, Rance, G A, Ardavan, A, Khlobystov, AN, Briggs, GAD, Porfyrakis, K
Format: Artikel
Sprache:eng
Schlagworte:
Amino acids
Assessments
Cage
Derivatives
Dimers
Fullerenes
Platforms
Quantum computing
Registers
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Zusammenfassung:Rattling the cage: The rapid one-pot double 1,3-dipolar cycloaddition reaction of the rare endohedral fullerene N[at]C sub(60) to an oligo(p-phenylene polyethylene) bis(aldehyde) using a novel amino acid derivative as an anchoring group is reported. The method provides the first example of a chemically linked, two-spin-center N[at]C sub(60)-N C sub(60) molecule (see picture). Assessment of this platform as an element of a quantum computing register is attractive.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201107490