Upgrading Pyrolysis Oil over Ni/HZSM-5 by Cascade Reactions

Upgrading Pyrolysis Oil over Ni/HZSM-5 by Cascade Reactions

Bio‐oil to hydrocarbon oil: An active, selective, and stable catalyst (Ni supported in zeolite HZSM‐5) allows the conversion of a wide variety of CO and CO bonds in n‐hexane‐extracted pyrolysis oil into hydrocarbons through a cascade of hydrogenation, hydrolysis, dehydration, and dehydroaromatizat...

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Veröffentlicht in:Angewandte Chemie International Edition 2012-06, Vol.51 (24), p.5935-5940
Hauptverfasser: Zhao, Chen, Lercher, Johannes A.
Format: Artikel
Sprache:eng
Schlagworte:
bio-oil
Cascades
Catalysis
Conversion
Hydrocarbons
Hydrocarbons - chemistry
hydrodeoxygenation
Hydrogenation
hydrogenolysis
Hydrolysis
Nickel
Nickel - chemistry
Oils - chemistry
phenolic compounds
Pyrolysis
Upgrading
Zeolites
Zeolites - chemistry
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Beschreibung
Zusammenfassung:Bio‐oil to hydrocarbon oil: An active, selective, and stable catalyst (Ni supported in zeolite HZSM‐5) allows the conversion of a wide variety of CO and CO bonds in n‐hexane‐extracted pyrolysis oil into hydrocarbons through a cascade of hydrogenation, hydrolysis, dehydration, and dehydroaromatization reactions. Quantitative yields of C5–C9 gasoline‐range hydrocarbons are obtained under mild conditions in water.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201108306