Knölker's Iron Complex: An Efficient In Situ Generated Catalyst for Reductive Amination of Alkyl Aldehydes and Amines
An aminated series: A well‐defined iron‐catalyzed reductive amination reaction of aldehydes and ketones with aliphatic amines using molecular hydrogen is presented. Under mild conditions, good yields for a broad range of alkyl ketones as well as aldehydes were achieved.
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Veröffentlicht in: | Angewandte Chemie International Edition 2012-05, Vol.51 (20), p.4976-4980 |
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creator | Pagnoux-Ozherelyeva, Anastassiya Pannetier, Nicolas Mbaye, Mbaye Diagne Gaillard, Sylvain Renaud, Jean-Luc |
description | An aminated series: A well‐defined iron‐catalyzed reductive amination reaction of aldehydes and ketones with aliphatic amines using molecular hydrogen is presented. Under mild conditions, good yields for a broad range of alkyl ketones as well as aldehydes were achieved. |
doi_str_mv | 10.1002/anie.201201360 |
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subjects | Aldehydes Aldehydes - chemistry Aliphatic amines Amination Amines Amines - chemical synthesis Amines - chemistry Catalysis Catalysts Coordination Complexes - chemistry homogeneous catalysis hydrogenation Iron Iron and steel industry Iron Compounds - chemistry Ketones Molecular Structure Stereoisomerism |
title | Knölker's Iron Complex: An Efficient In Situ Generated Catalyst for Reductive Amination of Alkyl Aldehydes and Amines |
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