Knölker's Iron Complex: An Efficient In Situ Generated Catalyst for Reductive Amination of Alkyl Aldehydes and Amines

Knölker's Iron Complex: An Efficient In Situ Generated Catalyst for Reductive Amination of Alkyl Aldehydes and Amines

An aminated series: A well‐defined iron‐catalyzed reductive amination reaction of aldehydes and ketones with aliphatic amines using molecular hydrogen is presented. Under mild conditions, good yields for a broad range of alkyl ketones as well as aldehydes were achieved.

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Veröffentlicht in:Angewandte Chemie International Edition 2012-05, Vol.51 (20), p.4976-4980
Hauptverfasser: Pagnoux-Ozherelyeva, Anastassiya, Pannetier, Nicolas, Mbaye, Mbaye Diagne, Gaillard, Sylvain, Renaud, Jean-Luc
Format: Artikel
Sprache:eng
Schlagworte:
Aldehydes
Aldehydes - chemistry
Aliphatic amines
Amination
Amines
Amines - chemical synthesis
Amines - chemistry
Catalysis
Catalysts
Coordination Complexes - chemistry
homogeneous catalysis
hydrogenation
Iron
Iron and steel industry
Iron Compounds - chemistry
Ketones
Molecular Structure
Stereoisomerism
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Beschreibung
Zusammenfassung:An aminated series: A well‐defined iron‐catalyzed reductive amination reaction of aldehydes and ketones with aliphatic amines using molecular hydrogen is presented. Under mild conditions, good yields for a broad range of alkyl ketones as well as aldehydes were achieved.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201201360