Self-Assembly of M sub(24)L sub(48) Polyhedra Based on Empirical Prediction
Critical structural switch: A small initial difference in the angle within bidentate ligands (see scheme) is amplified into an incommensurable difference in the resultant structures (M sub(12)L sub(24) or M sub(24)L sub(48)). This molecular-level emergent behavior was predicted from the empirical th...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2012-03, Vol.51 (13), p.3161-3163 |
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| container_issue | 13 |
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| container_title | Angewandte Chemie International Edition |
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| creator | Bunzen, Jens Iwasa, Junji Bonakdarzadeh, Pia Numata, Eri Rissanen, Kari Sato, Sota Fujita, Makoto |
| description | Critical structural switch: A small initial difference in the angle within bidentate ligands (see scheme) is amplified into an incommensurable difference in the resultant structures (M sub(12)L sub(24) or M sub(24)L sub(48)). This molecular-level emergent behavior was predicted from the empirical threshold of the ligand bend angle, determined by a ligand mixing experiment, for the critical M sub(12)L sub(24)/M sub(24 )L sub(48) switchover. |
| doi_str_mv | 10.1002/anie.201108731 |
| format | Article |
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This molecular-level emergent behavior was predicted from the empirical threshold of the ligand bend angle, determined by a ligand mixing experiment, for the critical M sub(12)L sub(24)/M sub(24 )L sub(48) switchover.</abstract><doi>10.1002/anie.201108731</doi></addata></record> |
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| subjects | Amplification Empirical analysis Ligands Polyhedra Polyhedrons Resultants Self assembly Switches Thresholds |
| title | Self-Assembly of M sub(24)L sub(48) Polyhedra Based on Empirical Prediction |
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