Self-Assembly of M sub(24)L sub(48) Polyhedra Based on Empirical Prediction

Self-Assembly of M sub(24)L sub(48) Polyhedra Based on Empirical Prediction

Critical structural switch: A small initial difference in the angle within bidentate ligands (see scheme) is amplified into an incommensurable difference in the resultant structures (M sub(12)L sub(24) or M sub(24)L sub(48)). This molecular-level emergent behavior was predicted from the empirical th...

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Veröffentlicht in:Angewandte Chemie International Edition 2012-03, Vol.51 (13), p.3161-3163
Hauptverfasser: Bunzen, Jens, Iwasa, Junji, Bonakdarzadeh, Pia, Numata, Eri, Rissanen, Kari, Sato, Sota, Fujita, Makoto
Format: Artikel
Sprache:eng
Schlagworte:
Amplification
Empirical analysis
Ligands
Polyhedra
Polyhedrons
Resultants
Self assembly
Switches
Thresholds
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Zusammenfassung:Critical structural switch: A small initial difference in the angle within bidentate ligands (see scheme) is amplified into an incommensurable difference in the resultant structures (M sub(12)L sub(24) or M sub(24)L sub(48)). This molecular-level emergent behavior was predicted from the empirical threshold of the ligand bend angle, determined by a ligand mixing experiment, for the critical M sub(12)L sub(24)/M sub(24 )L sub(48) switchover.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201108731