Syntheses, crystal structures, and magnetic properties of three new molecular solids based on bis(maleonitriledithiolate)Ni(III) monoanion and substituted chlorobenzyl-4-dimethylaminopyridinium

•Crystal structures of three molecular metals were obtained.•The Ni(III) ions of 1 form a non-uniform 1D magnetic chain.•The Ni(III) ions of 2 form a 1D uniform chain.•The [Ni(mnt)2]− anions of 3 show a stepwise structure.•Three molecular metals exhibit an interesting characteristic of spin-gap. Thr...

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Veröffentlicht in:Synthetic metals 2014-08, Vol.194, p.137-145
Hauptverfasser: Ye, Hui-Qing, Shi, Liang-Yuan, Zhang, Jin-Xuan, Hu, Ya-Lan, Huang, Rui-Kang, Lv, Xiong-Zhou, Zhou, Jia-Rong, Yang, Le-Min, Ni, Chun-Lin
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Sprache:eng
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Zusammenfassung:•Crystal structures of three molecular metals were obtained.•The Ni(III) ions of 1 form a non-uniform 1D magnetic chain.•The Ni(III) ions of 2 form a 1D uniform chain.•The [Ni(mnt)2]− anions of 3 show a stepwise structure.•Three molecular metals exhibit an interesting characteristic of spin-gap. Three new molecular solids, [nClBzPyN(CH3)2][Ni(mnt)2]([BzPyN(CH3)2]+=benzyl-4-dimethylaminopyridinium; mnt2−=maleonitriledithiolate; n=2(1), 3(2), 4(3)), have been prepared and characterized. The [Ni(mnt)2]− anions of 1 and 2 form a 1D column in which the former is non-uniform one with the Ni⋯Ni distances of 4.412 and 6.072Å, and the latter is uniform one with the distance of 7.352Å, while the ones of 3 show a stepwise structure through Ni⋯S, Ni⋯C, π⋯π, or C⋯N short interactions. The [2ClBzPyN(CH3)2]+ cations(C) and [Ni(mnt)2]− anions (A) of 1 stack into a 1D column with a ⋯ACCACCA⋯ sequence, while the cations stake into a 1D column via N⋯π and Cl⋯Cl short interactions for 2. The change of the chlorine position on the benzyl ring from ortho, meta to para-position results in the significant differences in stacking modes of these molecular solids. Magnetic susceptibility measurements in the temperature range 2–300K show that 1, 2 and 3 exhibit a spin gap transition around 172, 150 and 92K.
ISSN:0379-6779
1879-3290
DOI:10.1016/j.synthmet.2014.04.019