Gasification of Sugarcane Bagasse over Supported Ruthenium Catalysts in Supercritical Water

Gasification of sugarcane bagasse on activated-carbon- and titania-supported ruthenium (Ru/C and Ru/TiO2) catalysts in supercritical water was studied. Sugarcane bagasse was completely gasified to methane, carbon dioxide, and hydrogen over Ru/C and Ru/TiO2 catalysts at 673 K. The carbon yield of the...

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Veröffentlicht in:Energy & fuels 2012-06, Vol.26 (6), p.3179-3186
Hauptverfasser: Osada, Mitsumasa, Yamaguchi, Aritomo, Hiyoshi, Norihito, Sato, Osamu, Shirai, Masayuki
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Sprache:eng
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Zusammenfassung:Gasification of sugarcane bagasse on activated-carbon- and titania-supported ruthenium (Ru/C and Ru/TiO2) catalysts in supercritical water was studied. Sugarcane bagasse was completely gasified to methane, carbon dioxide, and hydrogen over Ru/C and Ru/TiO2 catalysts at 673 K. The carbon yield of the gas products from sugarcane bagasse, cellulose, and lignin over the Ru/TiO2 catalyst at a water density of 0.33 g cm–3 for 15 min was 50.3, 74.4, and 31.1 C %, respectively. In addition, it was observed that an increase in the water density enhanced the initial carbon yield of the gas products for 15 min. The recyclability of the Ru/C catalyst with complete gasification could make it a sustainable process.
ISSN:0887-0624
1520-5029
DOI:10.1021/ef300460c