Assembly and Stepwise Oxidation of Interpenetrated Coordination Cages Based on Phenothiazine

Assembly and Stepwise Oxidation of Interpenetrated Coordination Cages Based on Phenothiazine

A breath of fresh air is sufficient for the eightfold S‐monooxygenation of an interpenetrated double cage based on eight phenothiazine ligands and four square‐planar‐coordinated PdII cations. Besides these two cages, which were both characterized by X‐ray crystallography, an eightfold S‐dioxygenated...

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Veröffentlicht in:Angew. Chem. Int. Ed 2013-09, Vol.52 (38), p.10102-10106
Hauptverfasser: Frank, Marina, Hey, Jakob, Balcioglu, Ilker, Chen, Yu-Sheng, Stalke, Dietmar, Suenobu, Tomoyoshi, Fukuzumi, Shunichi, Frauendorf, Holm, Clever, Guido H.
Format: Artikel
Sprache:eng
Schlagworte:
Assembly
cage compounds
Cages
Cations
Crystallography
interpenetration
Ligands
Molecular Structure
Organic Chemicals - chemistry
Oxidation
Oxidation-Reduction
Phenothiazines
Phenothiazines - chemistry
redox chemistry
supramolecular chemistry
X-rays
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Zusammenfassung:A breath of fresh air is sufficient for the eightfold S‐monooxygenation of an interpenetrated double cage based on eight phenothiazine ligands and four square‐planar‐coordinated PdII cations. Besides these two cages, which were both characterized by X‐ray crystallography, an eightfold S‐dioxygenated double‐cage was obtained under harsher oxidation conditions.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201302536