Rhodium(III)-Catalyzed CC Coupling between Arenes and Aziridines by CH Activation

Making CC from CH: [{RhCp*Cl2}2]/AgSbF6 (Cp*=pentamethylcyclopentadienyl) can regioselectively catalyze the CC coupling of arenes with aziridines by a CH activation pathway. An eight‐membered rhodacyclic intermediate resulting from the insertion of the RhC bond into the aziridine was isolated....

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Veröffentlicht in:	Angewandte Chemie International Edition 2013-02, Vol.52 (9), p.2577-2580
Hauptverfasser:	Li, Xingwei, Yu, Songjie, Wang, Fen, Wan, Boshun, Yu, Xinzhang
Format:	Artikel
Sprache:	eng
Schlagworte:	Activation Aromatic compounds aziridines Bonding CC coupling CH activation Insertion Joining Pathways rhodium
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creator	Li, Xingwei Yu, Songjie Wang, Fen Wan, Boshun Yu, Xinzhang
description	Making CC from CH: [{RhCpCl2}2]/AgSbF6 (Cp=pentamethylcyclopentadienyl) can regioselectively catalyze the CC coupling of arenes with aziridines by a CH activation pathway. An eight‐membered rhodacyclic intermediate resulting from the insertion of the RhC bond into the aziridine was isolated.
doi_str_mv	10.1002/anie.201209887
format	Article
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subjects	Activation Aromatic compounds aziridines Bonding CC coupling CH activation Insertion Joining Pathways rhodium
title	Rhodium(III)-Catalyzed CC Coupling between Arenes and Aziridines by CH Activation
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