Rhodium(III)-Catalyzed CC Coupling between Arenes and Aziridines by CH Activation

Rhodium(III)-Catalyzed CC Coupling between Arenes and Aziridines by CH Activation

Making CC from CH: [{RhCp*Cl2}2]/AgSbF6 (Cp*=pentamethylcyclopentadienyl) can regioselectively catalyze the CC coupling of arenes with aziridines by a CH activation pathway. An eight‐membered rhodacyclic intermediate resulting from the insertion of the RhC bond into the aziridine was isolated....

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie International Edition 2013-02, Vol.52 (9), p.2577-2580
Hauptverfasser: Li, Xingwei, Yu, Songjie, Wang, Fen, Wan, Boshun, Yu, Xinzhang
Format: Artikel
Sprache:eng
Schlagworte:
Activation
Aromatic compounds
aziridines
Bonding
CC coupling
CH activation
Insertion
Joining
Pathways
rhodium
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Making CC from CH: [{RhCp*Cl2}2]/AgSbF6 (Cp*=pentamethylcyclopentadienyl) can regioselectively catalyze the CC coupling of arenes with aziridines by a CH activation pathway. An eight‐membered rhodacyclic intermediate resulting from the insertion of the RhC bond into the aziridine was isolated.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201209887