Synthesis of Functionalizable and Degradable Polymers by Ring-Opening Metathesis Polymerization

Synthesis of Functionalizable and Degradable Polymers by Ring-Opening Metathesis Polymerization

ROMP: A heterobicyclic olefin containing an oxazinone core is a new substrate for the ring‐opening metathesis polymerization (ROMP). The polymers produced undergo degradation when exposed to either acidic or basic conditions. Furthermore, a monomer that can be readily diversified to access degradabl...

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Veröffentlicht in:Angewandte Chemie International Edition 2013-05, Vol.52 (19), p.5061-5064
Hauptverfasser: Fishman, Joshua M., Kiessling, Laura L.
Format: Artikel
Sprache:eng
Schlagworte:
Bearing
Biocompatible Materials - chemical synthesis
Chemical synthesis
click chemistry
Cycloparaffins - chemistry
Decomposition reactions
degradable polymers
Degradation
Metathesis
Molecular Structure
Monomers
Olefins
oxazinone
Polymerization
Polymers
Polymers - chemical synthesis
ring-opening polymerization
Substrates
Synthesis
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Beschreibung
Zusammenfassung:ROMP: A heterobicyclic olefin containing an oxazinone core is a new substrate for the ring‐opening metathesis polymerization (ROMP). The polymers produced undergo degradation when exposed to either acidic or basic conditions. Furthermore, a monomer that can be readily diversified to access degradable polymers bearing tailored functionality was developed.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201300293