Thiourea-Mediated Regioselective Synthesis of Symmetrical and Unsymmetrical Diversified Thioethers

Thiourea-Mediated Regioselective Synthesis of Symmetrical and Unsymmetrical Diversified Thioethers

An efficient and simple thiourea-mediated regioselective synthesis of symmetrical and unsymmetrical diversified thioethers is reported. The regioselective reaction avoids byproduct formation and offers simplified methodology, wider applicability, and easy workability and an environmentally friendly...

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Veröffentlicht in:Industrial & engineering chemistry research 2014-05, Vol.53 (19), p.7866-7870
Hauptverfasser: Manivel, Pitchai, Prabakaran, Kamalakannan, Krishnakumar, Varadhan, Nawaz Khan, Fazlur-Rahman, Maiyalagan, Thandavarayan
Format: Artikel
Sprache:eng
Schlagworte:
Byproducts
Formations
Industrial engineering
Methodology
Sulfur
Synthesis
Thiols
Workability
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Beschreibung
Zusammenfassung:An efficient and simple thiourea-mediated regioselective synthesis of symmetrical and unsymmetrical diversified thioethers is reported. The regioselective reaction avoids byproduct formation and offers simplified methodology, wider applicability, and easy workability and an environmentally friendly approach toward symmetrical and unsymmetrical thioethers. The mechanism of formation of thiols and symmetrical and unsymmetrical thioethers involving a sulfur surrogate is described.
ISSN:0888-5885
1520-5045
DOI:10.1021/ie500119p