Domino Cycloaddition Organocascades of Dendralenes
Hooray Horeau! Highly enantioselective organocatalyzed Diels–Alder reaction cascades are disclosed for the first time. The reaction enables the efficient and rapid construction of enantiopure polycycles from simple achiral, acyclic polyenes.
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Veröffentlicht in: | Angewandte Chemie International Edition 2013-08, Vol.52 (32), p.8333-8336 |
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container_title | Angewandte Chemie International Edition |
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creator | Green, Nicholas J. Lawrence, Andrew L. Bojase, Gomotsang Willis, Anthony C. Paddon-Row, Michael N. Sherburn, Michael S. |
description | Hooray Horeau! Highly enantioselective organocatalyzed Diels–Alder reaction cascades are disclosed for the first time. The reaction enables the efficient and rapid construction of enantiopure polycycles from simple achiral, acyclic polyenes. |
doi_str_mv | 10.1002/anie.201302185 |
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subjects | Cascades Construction Cycloaddition Diels-Alder reactions hydrocarbons polycycles polyenes synthetic methods |
title | Domino Cycloaddition Organocascades of Dendralenes |
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