Domino Cycloaddition Organocascades of Dendralenes

Domino Cycloaddition Organocascades of Dendralenes

Hooray Horeau! Highly enantioselective organocatalyzed Diels–Alder reaction cascades are disclosed for the first time. The reaction enables the efficient and rapid construction of enantiopure polycycles from simple achiral, acyclic polyenes.

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Veröffentlicht in:Angewandte Chemie International Edition 2013-08, Vol.52 (32), p.8333-8336
Hauptverfasser: Green, Nicholas J., Lawrence, Andrew L., Bojase, Gomotsang, Willis, Anthony C., Paddon-Row, Michael N., Sherburn, Michael S.
Format: Artikel
Sprache:eng
Schlagworte:
Cascades
Construction
Cycloaddition
Diels-Alder reactions
hydrocarbons
polycycles
polyenes
synthetic methods
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Beschreibung
Zusammenfassung:Hooray Horeau! Highly enantioselective organocatalyzed Diels–Alder reaction cascades are disclosed for the first time. The reaction enables the efficient and rapid construction of enantiopure polycycles from simple achiral, acyclic polyenes.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201302185