Atomically Thin Tin Dioxide Sheets for Efficient Catalytic Oxidation of Carbon Monoxide

The thinner the better: SnO2 sheets that are five atomic layers thick are an efficient catalyst for the oxidation of CO (see picture). These sheets, which have 40 % surface atom occupancy and are fabricated by a scalable ethylenediamine‐assisted pathway, show remarkably improved catalytic performanc...

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Veröffentlicht in:Angewandte Chemie International Edition 2013-09, Vol.52 (40), p.10569-10572
Hauptverfasser: Sun, Yongfu, Lei, Fengcai, Gao, Shan, Pan, Bicai, Zhou, Jingfang, Xie, Yi
Format: Artikel
Sprache:eng
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Zusammenfassung:The thinner the better: SnO2 sheets that are five atomic layers thick are an efficient catalyst for the oxidation of CO (see picture). These sheets, which have 40 % surface atom occupancy and are fabricated by a scalable ethylenediamine‐assisted pathway, show remarkably improved catalytic performances compared to other SnO2 species, with the apparent activation energy lowered to 59.2 kJ mol−1 and the full‐conversion‐temperature lowered to 250 °C.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201305530