Atomically Thin Tin Dioxide Sheets for Efficient Catalytic Oxidation of Carbon Monoxide
The thinner the better: SnO2 sheets that are five atomic layers thick are an efficient catalyst for the oxidation of CO (see picture). These sheets, which have 40 % surface atom occupancy and are fabricated by a scalable ethylenediamine‐assisted pathway, show remarkably improved catalytic performanc...
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Veröffentlicht in: | Angewandte Chemie International Edition 2013-09, Vol.52 (40), p.10569-10572 |
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Hauptverfasser: | , , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | The thinner the better: SnO2 sheets that are five atomic layers thick are an efficient catalyst for the oxidation of CO (see picture). These sheets, which have 40 % surface atom occupancy and are fabricated by a scalable ethylenediamine‐assisted pathway, show remarkably improved catalytic performances compared to other SnO2 species, with the apparent activation energy lowered to 59.2 kJ mol−1 and the full‐conversion‐temperature lowered to 250 °C. |
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ISSN: | 1433-7851 1521-3773 |
DOI: | 10.1002/anie.201305530 |