Sandmeyer Trifluoromethylation of Arenediazonium Tetrafluoroborates
Copper capabilities: Diazonium salts are converted into the corresponding trifluoromethyl derivatives in the presence of a trifluoromethyl–copper complex generated in situ from CuSCN and the inexpensive, easy‐to‐use trifluoromethylating reagent Me3Si‐CF3 (see scheme). This Sandmeyer‐type reaction al...
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| Veröffentlicht in: | Angewandte Chemie International Edition 2013-07, Vol.52 (31), p.7972-7975 |
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| container_end_page | 7975 |
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| container_issue | 31 |
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| container_title | Angewandte Chemie International Edition |
| container_volume | 52 |
| creator | Danoun, Grégory Bayarmagnai, Bilguun Grünberg, Matthias F. Gooßen, Lukas J. |
| description | Copper capabilities: Diazonium salts are converted into the corresponding trifluoromethyl derivatives in the presence of a trifluoromethyl–copper complex generated in situ from CuSCN and the inexpensive, easy‐to‐use trifluoromethylating reagent Me3Si‐CF3 (see scheme). This Sandmeyer‐type reaction allows the straightforward synthesis of trifluoromethylated arenes and heteroarenes from the corresponding amines. |
| doi_str_mv | 10.1002/anie.201304276 |
| format | Article |
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| source | MEDLINE; Access via Wiley Online Library |
| subjects | AMINES Aromatic compounds Borates - chemistry CONVERTERS Coordination Complexes - chemistry Copper Copper - chemistry Copper converters Derivatives Diazonium Compounds - chemistry diazonium salts FABRICATION Fluorine - chemistry Methylation Sandmeyer reaction Synthesis trifluoromethylation |
| title | Sandmeyer Trifluoromethylation of Arenediazonium Tetrafluoroborates |
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