A Remarkable Organometallic Transformation on a Cage-Incarcerated Dinuclear Ruthenium Complex

Under confinement: Photosubstitution of a CO ligand with an alkyne on a dinuclear ruthenium carbonyl complex within a self‐assembled cage occurs without the cleavage of the photolabile RuRu bond. The resulting Ru–alkyne π complex is a reaction intermediate stabilized inside the cage. Outside the ca...

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Veröffentlicht in:	Angewandte Chemie International Edition 2012-11, Vol.51 (48), p.12029-12031
Hauptverfasser:	Horiuchi, Shinnosuke, Murase, Takashi, Fujita, Makoto
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkynes Bonding Cage cage compounds Carbon monoxide Cleavage host-guest systems Ligands organometallic chemistry photochemistry Ruthenium self-assembly Transformations
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creator	Horiuchi, Shinnosuke Murase, Takashi Fujita, Makoto
description	Under confinement: Photosubstitution of a CO ligand with an alkyne on a dinuclear ruthenium carbonyl complex within a self‐assembled cage occurs without the cleavage of the photolabile RuRu bond. The resulting Ru–alkyne π complex is a reaction intermediate stabilized inside the cage. Outside the cage, the π complex can be further transformed to a diruthenacyclopentenone framework by intramolecular CO insertion (see scheme).
doi_str_mv	10.1002/anie.201206325
format	Article
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subjects	Alkynes Bonding Cage cage compounds Carbon monoxide Cleavage host-guest systems Ligands organometallic chemistry photochemistry Ruthenium self-assembly Transformations
title	A Remarkable Organometallic Transformation on a Cage-Incarcerated Dinuclear Ruthenium Complex
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