Anodic Oxidation on a Boron-Doped Diamond Electrode Mediated by Methoxy Radicals

Anodic Oxidation on a Boron-Doped Diamond Electrode Mediated by Methoxy Radicals

Direct evidence: The existence of methoxy radical species formed during an anodic oxidation in MeOH on a boron‐doped diamond (BDD) electrode was confirmed by ESR spectroscopy. Effective production of a neolignan, licarin A, was accomplished by the BDD‐mediated anodic oxidation protocol (see picture)...

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Veröffentlicht in:Angewandte Chemie International Edition 2012-05, Vol.51 (22), p.5443-5446
Hauptverfasser: Sumi, Takenori, Saitoh, Tsuyoshi, Natsui, Keisuke, Yamamoto, Takashi, Atobe, Mahito, Einaga, Yasuaki, Nishiyama, Shigeru
Format: Artikel
Sprache:eng
Schlagworte:
Anodizing
boron-doped diamond electrode
Diamonds
electrochemistry
Electrodes
electrosynthesis
Pictures
Radicals
Spectroscopy
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Beschreibung
Zusammenfassung:Direct evidence: The existence of methoxy radical species formed during an anodic oxidation in MeOH on a boron‐doped diamond (BDD) electrode was confirmed by ESR spectroscopy. Effective production of a neolignan, licarin A, was accomplished by the BDD‐mediated anodic oxidation protocol (see picture).
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201200878