Sequence-Dependent Assembly to Control Molecular Interface Properties

Sequence-Dependent Assembly to Control Molecular Interface Properties

Variation's what you need: Variation of the assembly sequence in which layers of two isostructural metal complexes are built up leads to molecular materials with electrochemical properties that depend on the assembly sequence. These properties vary from reversible electron transfer to unidirect...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Angewandte Chemie International Edition 2013-01, Vol.52 (2), p.704-709
Hauptverfasser: de Ruiter, Graham, Lahav, Michal, Keisar, Hodaya, van der Boom, Milko E.
Format: Artikel
Sprache:eng
Schlagworte:
Assembly
Charge
Charge transfer
electrochemistry
Electron transfer
interfaces
Lead (metal)
metal complexes
molecular materials
Self assembly
sequence-dependent assembly
Strategy
Trapping
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Variation's what you need: Variation of the assembly sequence in which layers of two isostructural metal complexes are built up leads to molecular materials with electrochemical properties that depend on the assembly sequence. These properties vary from reversible electron transfer to unidirectional current flows and even charge trapping. The sequence‐dependent assembly strategy has implications for various disciplines that involve self‐assembly.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201207467