A Generic One-Pot Route to Acyclic Two-Coordinate Silylenes from Silicon(IV) Precursors: Synthesis and Structural Characterization of a Silylsilylene

A Generic One-Pot Route to Acyclic Two-Coordinate Silylenes from Silicon(IV) Precursors: Synthesis and Structural Characterization of a Silylsilylene

Si in sight: A one‐pot, single‐step synthesis of an acyclic silylsilylene, Si{Si(SiMe3)3}{N(SiMe3)Dipp} (Dipp=2,6‐iPr2C6H3), from a silicon(IV) starting material is reported, together with evidence for a mechanism involving alkali metal silylenoid intermediates.

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Veröffentlicht in:Angewandte Chemie International Edition 2013-01, Vol.52 (2), p.568-571
Hauptverfasser: Protchenko, Andrey V., Schwarz, Andrew D., Blake, Matthew P., Jones, Cameron, Kaltsoyannis, Nikolas, Mountford, Philip, Aldridge, Simon
Format: Artikel
Sprache:eng
Schlagworte:
Alkali metals
Dipping
gallium
Precursors
reduction
Silicon
silylenes
Structural analysis
subvalent compounds
Synthesis
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Zusammenfassung:Si in sight: A one‐pot, single‐step synthesis of an acyclic silylsilylene, Si{Si(SiMe3)3}{N(SiMe3)Dipp} (Dipp=2,6‐iPr2C6H3), from a silicon(IV) starting material is reported, together with evidence for a mechanism involving alkali metal silylenoid intermediates.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201208554