Palladium-Induced Pyrrolic Rearrangement of a Singly to a Doubly N-Confused [26]Hexaphyrin

Palladium-Induced Pyrrolic Rearrangement of a Singly to a Doubly N-Confused [26]Hexaphyrin

A pyrrolic rearrangement reaction of singly N‐confused [26]hexaphyrin mediated by PdCl2 afforded doubly N‐confused [26]hexaphyrin bis(PdII) complex. The bis(PdII) complex is a rare example of an aromatic compound with definite non‐degenerate HOMOs and LUMOs.

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Veröffentlicht in:Angewandte Chemie International Edition 2013-07, Vol.52 (27), p.6940-6943
Hauptverfasser: Gokulnath, Sabapathi, Nishimura, Keiichi, Toganoh, Motoki, Mori, Shigeki, Furuta, Hiroyuki
Format: Artikel
Sprache:eng
Schlagworte:
Aromatic compounds
aromaticity
expanded porphyrins
hexaphyrins
macrocycles
palladium
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Zusammenfassung:A pyrrolic rearrangement reaction of singly N‐confused [26]hexaphyrin mediated by PdCl2 afforded doubly N‐confused [26]hexaphyrin bis(PdII) complex. The bis(PdII) complex is a rare example of an aromatic compound with definite non‐degenerate HOMOs and LUMOs.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201302955