Structural Evidence for Undecabromide [Br sub(11)] super(-)
Spreading the charge: Besides iodine, few of the polyhalogen anions have been structurally characterized. Remarkably, the highest known ratio of elements-to-charge has now been found in the undecabromide [Br sub(11)] super(-). This new polybromide monoanion has been prepared in pure halogen and was...
Gespeichert in:
Veröffentlicht in: | Angewandte Chemie International Edition 2013-04, Vol.52 (18), p.4937-4940 |
---|---|
Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | Spreading the charge: Besides iodine, few of the polyhalogen anions have been structurally characterized. Remarkably, the highest known ratio of elements-to-charge has now been found in the undecabromide [Br sub(11)] super(-). This new polybromide monoanion has been prepared in pure halogen and was structurally characterized by single-crystal X-ray diffraction, Raman spectroscopy (see picture), and quantum-chemical methods. |
---|---|
ISSN: | 1433-7851 1521-3773 |
DOI: | 10.1002/anie.201209928 |