Radical polymerization of 2,3-dimethyl-1,3-butadiene in coordination nanochannels

Radical polymerization of 2,3-dimethyl-1,3-butadiene in coordination nanochannels

Radical polymerization of unpolymerizable sterically hindered butadiene was successfully performed in the nanochannels of porous coordination polymers because of the effective suppression of unfavourable termination reactions. Microstructures of the resulting polymer could also be tuned depending on...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2015-06, Vol.51 (48), p.9892-9895
Hauptverfasser: Uemura, Takashi, Nakanishi, Ryo, Mochizuki, Shuto, Murata, Yasujiro, Kitagawa, Susumu
Format: Artikel
Sprache:eng
Schlagworte:
Butadiene
Coordination polymers
Microstructure
Nanostructure
Polymerization
Radicals
Termination (polymerization)
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Zusammenfassung:Radical polymerization of unpolymerizable sterically hindered butadiene was successfully performed in the nanochannels of porous coordination polymers because of the effective suppression of unfavourable termination reactions. Microstructures of the resulting polymer could also be tuned depending on the structure of the porous hosts.
ISSN:1359-7345
1364-548X
DOI:10.1039/c5cc01933h