Induced Self-Assembly of a Tetrathiafulvalene-Based Open-Shell Dyad through Intramolecular Electron Transfer

Induced Self-Assembly of a Tetrathiafulvalene-Based Open-Shell Dyad through Intramolecular Electron Transfer

An organic switch: An open‐shell dyad, consisting of an electron acceptor perchlorotriphenylmethyl radical unit linked to an electron π‐donor tetrathiafulvalene unit through a vinylene π‐bridge, was synthesized (see picture). The self‐assembly of the dyad in solution induced by its intramolecular el...

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Veröffentlicht in:Angewandte Chemie International Edition 2012-10, Vol.51 (44), p.11024-11028
Hauptverfasser: Guasch, Judith, Grisanti, Luca, Lloveras, Vega, Vidal-Gancedo, José, Souto, Manuel, Morales, Dayana C., Vilaseca, Marta, Sissa, Cristina, Painelli, Anna, Ratera, Imma, Rovira, Concepció, Veciana, Jaume
Format: Artikel
Sprache:eng
Schlagworte:
Electron transfer
Electrons
ESR spectroscopy
Heterocyclic Compounds - chemical synthesis
Heterocyclic Compounds - chemistry
Molecular Structure
Pictures
Radicals
Self assembly
supramolecular chemistry
Switches
Temperature
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Zusammenfassung:An organic switch: An open‐shell dyad, consisting of an electron acceptor perchlorotriphenylmethyl radical unit linked to an electron π‐donor tetrathiafulvalene unit through a vinylene π‐bridge, was synthesized (see picture). The self‐assembly of the dyad in solution induced by its intramolecular electron transfer was studied.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201203448