Control of Silver(I)-Dialkyl Chalcogenide Coordination by a Synthetic Cavity

Control of Silver(I)-Dialkyl Chalcogenide Coordination by a Synthetic Cavity

The discrete cavity of a self‐assembled palladium–tris(4‐pyridyl)triazine cage dictates the ratio of metal, ligand, and a non‐coordinative molecule in the formation of silver(I)–dialkyl chalcogenide (Et, nBu; S, Se) complexes and defines their coordination arrangement. Complexed in a complex: Comple...

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Veröffentlicht in:Angewandte Chemie International Edition 2014-10, Vol.53 (43), p.11510-11513
Hauptverfasser: Kohyama, Yuh, Murase, Takashi, Fujita, Makoto
Format: Artikel
Sprache:eng
Schlagworte:
Cage
cage compounds
Chalcogenides
chalcogens
Complexation
Formations
Holes
host-guest systems
Ligands
molecular recognition
silver
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Zusammenfassung:The discrete cavity of a self‐assembled palladium–tris(4‐pyridyl)triazine cage dictates the ratio of metal, ligand, and a non‐coordinative molecule in the formation of silver(I)–dialkyl chalcogenide (Et, nBu; S, Se) complexes and defines their coordination arrangement. Complexed in a complex: Complexation of a silver(I) ion with dialkyl chalcogenides is performed in the cavity of a self‐assembled cage. This method modulates the number and geometry of the chalcogenides coordinated to silver(I) and generates a metal–organic proximal state.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201406224