Tandem Synthesis of Photoactive Benzodifuran Moieties in the Formation of Microporous Organic Networks

Tandem Synthesis of Photoactive Benzodifuran Moieties in the Formation of Microporous Organic Networks

Tiny pores: Benzodifuran moieties were introduced into microporous organic networks (MONs) through a tandem process consisting of Sonogashira coupling of 1,3,5‐triethynylbenzene and 2,5‐diiodo‐1,4‐hydroquinone and intramolecular cyclization. The resultant benzodifuran‐containing MON showed promising...

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Veröffentlicht in:Angewandte Chemie International Edition 2013-06, Vol.52 (24), p.6228-6232
Hauptverfasser: Kang, Narae, Park, Ji Hoon, Ko, Kyoung Chul, Chun, Jiseul, Kim, Eunchul, Shin, Hee-Won, Lee, Sang Moon, Kim, Hae Jin, Ahn, Tae Kyu, Lee, Jin Yong, Son, Seung Uk
Format: Artikel
Sprache:eng
Schlagworte:
Amines
benzodifuran
Conversion
cross-coupling
Imines
Joining
microporous materials
Networks
photocatalyst
Porosity
Resultants
Synthesis
tandem synthesis
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Zusammenfassung:Tiny pores: Benzodifuran moieties were introduced into microporous organic networks (MONs) through a tandem process consisting of Sonogashira coupling of 1,3,5‐triethynylbenzene and 2,5‐diiodo‐1,4‐hydroquinone and intramolecular cyclization. The resultant benzodifuran‐containing MON showed promising photocatalytic activities in the oxidative conversion of primary amines into imines.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201300655