Rhodium(I)-Catalyzed Redox-Economic Cross-Coupling of Carboxylic Acids with Arenes Directed by N-Containing Groups

Marked absent: The pseudo‐oxidative decarboxylative coupling of carboxylic acids and arenes using rhodium(I) in the absence of an oxidant is described. The study offers a new convenient method for the construction of C sp 2C sp 2/C sp 3 bonds.

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Bibliographische Detailangaben
Veröffentlicht in:	Angewandte Chemie International Edition 2013-02, Vol.52 (7), p.2063-2067
Hauptverfasser:	Pan, Fei, Lei, Zhi-Quan, Wang, Hui, Li, Hu, Sun, Jian, Shi, Zhang-Jie
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic compounds biaryls Carbon - chemistry Carboxylic acids Carboxylic Acids - chemistry Catalysis Construction CH activation decarbonylation Joining Nitrogen - chemistry Oxidants Oxidation-Reduction Oxidizing agents Quantum Theory rhodium Rhodium - chemistry
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Beschreibung
Zusammenfassung:	Marked absent: The pseudo‐oxidative decarboxylative coupling of carboxylic acids and arenes using rhodium(I) in the absence of an oxidant is described. The study offers a new convenient method for the construction of C sp 2C sp 2/C sp 3 bonds.
ISSN:	1433-7851 1521-3773
DOI:	10.1002/anie.201208362