Template Assembly of Spin Crossover One-Dimensional Nanowires

Template Assembly of Spin Crossover One-Dimensional Nanowires

Wired for action: An alumina‐based template method produces nanowires of an alkylated mononuclear spin‐crossover FeIII complex. The wires can be isolated by dissolving the template in acid without decomposition of the product, and have a narrow distribution of diameter widths in the range of 80–100 ...

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Veröffentlicht in:Angewandte Chemie International Edition 2012-11, Vol.51 (48), p.11995-11999
Hauptverfasser: Martinho, Paulo N., Lemma, Tibebe, Gildea, Brendan, Picardi, Gennaro, Müller-Bunz, Helge, Forster, Robert J., Keyes, Tia E., Redmond, Gareth, Morgan, Grace G.
Format: Artikel
Sprache:eng
Schlagworte:
Assembly
Atomic force microscopy
Crossovers
data storage
Electronics
iron
Joining
Nanowires
Raman spectroscopy
spin crossover
template synthesis
Wire
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Beschreibung
Zusammenfassung:Wired for action: An alumina‐based template method produces nanowires of an alkylated mononuclear spin‐crossover FeIII complex. The wires can be isolated by dissolving the template in acid without decomposition of the product, and have a narrow distribution of diameter widths in the range of 80–100 nm. Electronic characterization of a single wire is possible by using Raman spectroscopy coupled to AFM (see picture).
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201205122