Iron-Catalyzed, Atom-Economical, Chemo- and Regioselective Alkene Hydroboration with Pinacolborane

Iron-Catalyzed, Atom-Economical, Chemo- and Regioselective Alkene Hydroboration with Pinacolborane

Precious iron: A new PNN iron complex has been developed for use in an iron‐catalyzed alkene hydroboration reaction under mild conditions. The environmentally friendly and earth‐abundant iron catalyst system is superior to precious‐metal systems in terms of efficiency and selectivity for α‐olefin hy...

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Veröffentlicht in:Angewandte Chemie International Edition 2013-03, Vol.52 (13), p.3676-3680
Hauptverfasser: Zhang, Lei, Peng, Dongjie, Leng, Xuebing, Huang, Zheng
Format: Artikel
Sprache:eng
Schlagworte:
alkylboronates
Catalysts
homogeneous catalysis
Hydroboration
Iron
Olefins
Selectivity
synthetic methods
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Beschreibung
Zusammenfassung:Precious iron: A new PNN iron complex has been developed for use in an iron‐catalyzed alkene hydroboration reaction under mild conditions. The environmentally friendly and earth‐abundant iron catalyst system is superior to precious‐metal systems in terms of efficiency and selectivity for α‐olefin hydroborations with pinacolborane.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201210347