Gold-Catalyzed Rearrangement of Allylic Oxonium Ylides: Efficient Synthesis of Highly Functionalized Dihydrofuran-3-ones
“Diazo” not needed: The title reaction results in the rearrangement of oxonium ylides, which were prepared from readily available homopropargylic allylic ethers instead of diazo compounds, through two different mechanisms: a concerted 2,3‐sigmatropic rearrangement, or a stepwise 1,4‐allyl migration...
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Veröffentlicht in: | Angewandte Chemie International Edition 2013-04, Vol.52 (15), p.4198-4202 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | “Diazo” not needed: The title reaction results in the rearrangement of oxonium ylides, which were prepared from readily available homopropargylic allylic ethers instead of diazo compounds, through two different mechanisms: a concerted 2,3‐sigmatropic rearrangement, or a stepwise 1,4‐allyl migration followed by a Claisen rearrangement (see scheme). |
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ISSN: | 1433-7851 1521-3773 |
DOI: | 10.1002/anie.201208305 |