Transfer of Aryl Halide to Alkyl Halide: Reductive Elimination of Alkylhalide from Alkylpalladium Halides Containing syn-β-Hydrogen Atoms

β‐Hydride ion is a well‐accepted elementary step for catalytic cycles in organometallic chemistry. It is usually anticipated that alkylpalladium halides containing syn‐β‐hydrogen atoms will undergo β‐hydride ion to afford the Heck‐type products. However, this study discloses that the above general k...

Ausführliche Beschreibung

Bibliographische Detailangaben

Veröffentlicht in:	Angewandte Chemie 2014-12, Vol.126 (52), p.14761-14765
Hauptverfasser:	Hao, Wei, Wei, Junnian, Geng, Weizhi, Zhang, Wen-Xiong, Xi, Zhenfeng
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic compounds Cases (containers) Catalysis Catalysts Eliminierungen Halides Iod Ligandeneffekte Metalorganic compounds Palladium Synthesemethoden
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!