Thiyl Radicals: From Simple Radical Additions to Asymmetric Catalysis

Thiyl Radicals: From Simple Radical Additions to Asymmetric Catalysis

Thiyl radicals at play: Thiyls are significant free‐radical intermediates both in biology and chemistry. The recent search for new enantioselective methods in radical chemistry has led to the inclusion of these radicals in the toolbox of chiral organocatalysts.

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Veröffentlicht in:Angewandte Chemie International Edition 2014-12, Vol.53 (50), p.13660-13662
Hauptverfasser: Subramanian, Hariharaputhiran, Moorthy, Ramkumar, Sibi, Mukund P.
Format: Artikel
Sprache:eng
Schlagworte:
asymmetric catalysis
Asymmetry
Biology
Catalysis
enantioselectivity
Free Radicals - chemistry
Inclusions
Radicals
Searching
Sulfhydryl Compounds - chemistry
synthetic methods
thiols
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Zusammenfassung:Thiyl radicals at play: Thiyls are significant free‐radical intermediates both in biology and chemistry. The recent search for new enantioselective methods in radical chemistry has led to the inclusion of these radicals in the toolbox of chiral organocatalysts.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201408781