Maximizing Coordinative and Electronic Unsaturation: Three-Coordinate Dicationic Platinum Complexes

Maximizing Coordinative and Electronic Unsaturation: Three-Coordinate Dicationic Platinum Complexes

Halide ion from cationic base‐stabilized borylene complexes led to extremely electronically and coordinatively unsaturated platinum complexes. The formally 14‐electron borylene complexes show no agostic interactions with the phosphine ligands, and only small Lewis donor ligands could be added to the...

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Veröffentlicht in:Angewandte Chemie International Edition 2013-03, Vol.52 (10), p.2981-2984
Hauptverfasser: Braunschweig, Holger, Brenner, Peter, Dewhurst, Rian D., Jimenez-Halla, J. Oscar C., Kupfer, Thomas, Rais, Daniela, Uttinger, Katharina
Format: Artikel
Sprache:eng
Schlagworte:
boron
borylenes
Cationic
cationic complexes
coordination chemistry
Donors (electronic)
Electronics
Halides
Ligands
Phosphines
Platinum
Unsaturated
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Beschreibung
Zusammenfassung:Halide ion from cationic base‐stabilized borylene complexes led to extremely electronically and coordinatively unsaturated platinum complexes. The formally 14‐electron borylene complexes show no agostic interactions with the phosphine ligands, and only small Lewis donor ligands could be added to the Pt center.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201209717