Evidence of Diamond Nanowires Formed inside Carbon Nanotubes from Diamantane Dicarboxylic Acid

Evidence of Diamond Nanowires Formed inside Carbon Nanotubes from Diamantane Dicarboxylic Acid

Carbon is a girl′s best friend: Carbon‐based nanowires have been produced during thermal annealing of diamantane‐4,9‐dicarboxylic acid in carbon nanotubes under hydrogen atmosphere (see scheme). HR‐TEM images, Raman spectra, and structural transformations observed under an intense electron beam sugg...

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Veröffentlicht in:Angewandte Chemie International Edition 2013-03, Vol.52 (13), p.3717-3721
Hauptverfasser: Zhang, Jinying, Zhu, Zhen, Feng, Yanquan, Ishiwata, Hitoshi, Miyata, Yasumitsu, Kitaura, Ryo, Dahl, Jeremy E. P., Carlson, Robert M. K., Fokina, Natalie A., Schreiner, Peter R., Tománek, David, Shinohara, Hisanori
Format: Artikel
Sprache:eng
Schlagworte:
Annealing
Carbon
Carbon nanotubes
diamond nanowires
diamondoids
Diamonds
Dicarboxylic acids
Nanowires
Raman spectra
Transformations
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Zusammenfassung:Carbon is a girl′s best friend: Carbon‐based nanowires have been produced during thermal annealing of diamantane‐4,9‐dicarboxylic acid in carbon nanotubes under hydrogen atmosphere (see scheme). HR‐TEM images, Raman spectra, and structural transformations observed under an intense electron beam suggest that the as‐produced carbon‐based nanowires are sp3 diamond nanowires, consistent with our computational results.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201209192