Palladium-Catalyzed Oxidative Carbonylation of N-Allylamines for the Synthesis of [beta]-Lactams
[beta]-Lactam scaffolds are considered to be ideal building blocks for the synthesis of nitrogen-containing compounds. A new palladium-catalyzed oxidative carbonylation of N-allylamines for the synthesis of [alpha]-methylene-[beta]-lactams is reported. DFT calculations suggest that the formation of...
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| Veröffentlicht in: | Angewandte Chemie 2014-02, Vol.126 (9), p.2475-2478 |
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| container_end_page | 2478 |
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| container_issue | 9 |
| container_start_page | 2475 |
| container_title | Angewandte Chemie |
| container_volume | 126 |
| creator | Li, Wu Liu, Chao Zhang, Heng Ye, Keyin Zhang, Guanghui Zhang, Wangzheng Duan, Zhengli You, Shuli Lei, Aiwen |
| description | [beta]-Lactam scaffolds are considered to be ideal building blocks for the synthesis of nitrogen-containing compounds. A new palladium-catalyzed oxidative carbonylation of N-allylamines for the synthesis of [alpha]-methylene-[beta]-lactams is reported. DFT calculations suggest that the formation of [beta]-lactams via a four-membered-ring transition state is favorable. [PUBLICATION ABSTRACT] |
| doi_str_mv | 10.1002/ange.201309081 |
| format | Article |
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A new palladium-catalyzed oxidative carbonylation of N-allylamines for the synthesis of [alpha]-methylene-[beta]-lactams is reported. DFT calculations suggest that the formation of [beta]-lactams via a four-membered-ring transition state is favorable. [PUBLICATION ABSTRACT]</description><identifier>ISSN: 0044-8249</identifier><identifier>EISSN: 1521-3757</identifier><identifier>DOI: 10.1002/ange.201309081</identifier><language>eng ; ger</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Beta ; Carbonyls ; Chemistry ; Formations ; Mathematical analysis ; Scaffolds ; Synthesis</subject><ispartof>Angewandte Chemie, 2014-02, Vol.126 (9), p.2475-2478</ispartof><rights>Copyright © 2014 WILEY-VCH Verlag GmbH & Co. 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A new palladium-catalyzed oxidative carbonylation of N-allylamines for the synthesis of [alpha]-methylene-[beta]-lactams is reported. DFT calculations suggest that the formation of [beta]-lactams via a four-membered-ring transition state is favorable. [PUBLICATION ABSTRACT]</description><subject>Beta</subject><subject>Carbonyls</subject><subject>Chemistry</subject><subject>Formations</subject><subject>Mathematical analysis</subject><subject>Scaffolds</subject><subject>Synthesis</subject><issn>0044-8249</issn><issn>1521-3757</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNpdj8FLwzAYxYMoOKdXzwEvXjK_pEna7ziKTmE4Yd5E5tc21Y60nU0rzr_eip48PX7w4_EeY-cSZhJAXVHz6mYKZAQIiTxgE2mUFFFs4kM2AdBaJErjMTsJYQsAVsU4YS8P5D0V1VCLlHry-y9X8NVnVVBffTieUpe1zd6P1Da8Lfm9mHs_cl01LvCy7Xj_5vh634wRqvCjPGWup2expLynOpyyo5J8cGd_OWXrm-vH9FYsV4u7dL4UOytRWFmYgqxyCFGpXawwsSXK2GjMDGinsiRRBl1OGYE1RlKeR1YrXSChpWjKLn9bd137PrjQb-oq5G681rh2CBsZA2CSIOKoXvxTt-3QNeO2jTQAxiAYGX0D3Yhj1g</recordid><startdate>20140224</startdate><enddate>20140224</enddate><creator>Li, Wu</creator><creator>Liu, Chao</creator><creator>Zhang, Heng</creator><creator>Ye, Keyin</creator><creator>Zhang, Guanghui</creator><creator>Zhang, Wangzheng</creator><creator>Duan, Zhengli</creator><creator>You, Shuli</creator><creator>Lei, Aiwen</creator><general>Wiley Subscription Services, Inc</general><scope>7SR</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>L7M</scope></search><sort><creationdate>20140224</creationdate><title>Palladium-Catalyzed Oxidative Carbonylation of N-Allylamines for the Synthesis of [beta]-Lactams</title><author>Li, Wu ; Liu, Chao ; Zhang, Heng ; Ye, Keyin ; Zhang, Guanghui ; Zhang, Wangzheng ; Duan, Zhengli ; You, Shuli ; Lei, Aiwen</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p619-61d5da62e903f4e72986f917549b504e2b88259ecaba06551acc36424d9a96a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng ; ger</language><creationdate>2014</creationdate><topic>Beta</topic><topic>Carbonyls</topic><topic>Chemistry</topic><topic>Formations</topic><topic>Mathematical analysis</topic><topic>Scaffolds</topic><topic>Synthesis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Wu</creatorcontrib><creatorcontrib>Liu, Chao</creatorcontrib><creatorcontrib>Zhang, Heng</creatorcontrib><creatorcontrib>Ye, Keyin</creatorcontrib><creatorcontrib>Zhang, Guanghui</creatorcontrib><creatorcontrib>Zhang, Wangzheng</creatorcontrib><creatorcontrib>Duan, Zhengli</creatorcontrib><creatorcontrib>You, Shuli</creatorcontrib><creatorcontrib>Lei, Aiwen</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Angewandte Chemie</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Wu</au><au>Liu, Chao</au><au>Zhang, Heng</au><au>Ye, Keyin</au><au>Zhang, Guanghui</au><au>Zhang, Wangzheng</au><au>Duan, Zhengli</au><au>You, Shuli</au><au>Lei, Aiwen</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Palladium-Catalyzed Oxidative Carbonylation of N-Allylamines for the Synthesis of [beta]-Lactams</atitle><jtitle>Angewandte Chemie</jtitle><date>2014-02-24</date><risdate>2014</risdate><volume>126</volume><issue>9</issue><spage>2475</spage><epage>2478</epage><pages>2475-2478</pages><issn>0044-8249</issn><eissn>1521-3757</eissn><abstract>[beta]-Lactam scaffolds are considered to be ideal building blocks for the synthesis of nitrogen-containing compounds. 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| issn | 0044-8249 1521-3757 |
| language | eng ; ger |
| recordid | cdi_proquest_miscellaneous_1700988999 |
| source | Wiley Online Library All Journals |
| subjects | Beta Carbonyls Chemistry Formations Mathematical analysis Scaffolds Synthesis |
| title | Palladium-Catalyzed Oxidative Carbonylation of N-Allylamines for the Synthesis of [beta]-Lactams |
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