Diaryl Selenide Catalyzed Vicinal Trifluoromethylthioamination of Alkenes

Diaryl Selenide Catalyzed Vicinal Trifluoromethylthioamination of Alkenes

An efficient approach to vicinal trifluoromethylthioamination of alkenes with a broad substrate scope catalyzed by electron-rich diaryl selenide has been developed. This intermolecular amination strategy was successfully applied to SCF3-esterification of alkenes using weak acids as nucleophiles.

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Veröffentlicht in:Organic letters 2015-07, Vol.17 (14), p.3620-3623
Hauptverfasser: Luo, Jie, Zhu, Zechen, Liu, Yannan, Zhao, Xiaodan
Format: Artikel
Sprache:eng
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Zusammenfassung:An efficient approach to vicinal trifluoromethylthioamination of alkenes with a broad substrate scope catalyzed by electron-rich diaryl selenide has been developed. This intermolecular amination strategy was successfully applied to SCF3-esterification of alkenes using weak acids as nucleophiles.
ISSN:1523-7060
1523-7052
DOI:10.1021/acs.orglett.5b01727