Investigation into a Pour Point Depressant for Shengli Crude Oil

A new-style pour point depressant (PPD) for crude oil was prepared by mixing the aminated copolymer and the composite commercial ethylene–vinyl acetate copolymers (EVA) in fixed proportion. The aminated copolymer was synthesized by amination of terpolymer copolymerized with monomers octadecyl acryla...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Industrial & engineering chemistry research 2012-09, Vol.51 (36), p.11605-11612
Hauptverfasser: Fang, Long, Zhang, Xiaodong, Ma, Jinhai, Zhang, Botao
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A new-style pour point depressant (PPD) for crude oil was prepared by mixing the aminated copolymer and the composite commercial ethylene–vinyl acetate copolymers (EVA) in fixed proportion. The aminated copolymer was synthesized by amination of terpolymer copolymerized with monomers octadecyl acrylate, maleic anhydride, and vinyl acetate. Moreover, the aminated copolymer was characterized by Fourier transform infrared (FTIR) spectroscopy, 1H nuclear magnetic resonance (1H NMR), and gel permeation chromatography (GPC). The interaction between components of the crude oil and the PPD was investigated by FTIR, differential scanning calorimetry (DSC), and cross-polarized light microscopy. The results showed that the PPD could form asphaltene–PPD–resin agglomerates. The new agglomerates became the efficient nucleator of the crude oil beneficiated with PPD. They changed the process of wax crystallization and greatly depressed the pour point of the crude oil.
ISSN:0888-5885
1520-5045
DOI:10.1021/ie301018r