The organic-rich carbonaceous component of dust aggregates in circumstellar disks: Effects of its carbonization on infrared spectral features of its magnesium-rich olivine counterpart

•We compute infrared (IR) spectra of dust aggregates in circumstellar environments.•The effect of carbonaceous material on IR spectra of dust was overlooked previously.•The degree of carbonization determines the positions of IR olivine peaks.•At least one third of the organic refractory component su...

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Veröffentlicht in:Icarus (New York, N.Y. 1962) N.Y. 1962), 2014-04, Vol.232, p.133-140
1. Verfasser: Kimura, Hiroshi
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Sprache:eng
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Zusammenfassung:•We compute infrared (IR) spectra of dust aggregates in circumstellar environments.•The effect of carbonaceous material on IR spectra of dust was overlooked previously.•The degree of carbonization determines the positions of IR olivine peaks.•At least one third of the organic refractory component suffered from carbonization. We model dust in comets, protoplanetary disks, and debris disks as aggregates consisting of submicron-sized grains with a silicate core and an organic-rich carbonaceous mantle. By computing the infrared (IR) spectra of the aggregates, we show that the degree of carbonization determines the positions of infrared peaks characteristic of magnesium-rich crystalline silicates. We discuss our results in terms of processing of organic materials by ultraviolet irradiation, ion bombardments, and thermal devolatilization. A comparison between the model IR spectra of the aggregates and the observed spectra of dust in circumstellar disks reveals that at least one third of the organic refractory component has suffered from carbonization in a very short timescale.
ISSN:0019-1035
1090-2643
DOI:10.1016/j.icarus.2014.01.009