Chromogenic Chemodosimeter for Highly Selective Detection of Cyanide in Water and Blood Plasma Based on Si–O Cleavage in the Micellar System

A novel silylated imine was designed to act efficiently in a chemodosimeter approach for the selective detection of cyanide in an aqueous micellar CTABr solution. This simple system allows the detection of cyanide, with high sensitivity and specific selectivity, in water and in human blood plasma.

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Bibliographische Detailangaben
Veröffentlicht in:	Analytical chemistry (Washington) 2015-01, Vol.87 (1), p.362-366
Hauptverfasser:	Nicoleti, Celso R, Nandi, Leandro G, Machado, Vanderlei G
Format:	Artikel
Sprache:	eng
Schlagworte:	Analytical chemistry Aqueous solutions Blood plasma Cetrimonium Compounds - chemistry Chemical compounds Cleavage Cyanides Cyanides - analysis Human Humans Imines Imines - chemistry Micelles Plasma Plasma - chemistry Selectivity Silanes - chemistry Spectrophotometry, Ultraviolet Surface-Active Agents - chemistry Water Water - analysis
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Beschreibung
Zusammenfassung:	A novel silylated imine was designed to act efficiently in a chemodosimeter approach for the selective detection of cyanide in an aqueous micellar CTABr solution. This simple system allows the detection of cyanide, with high sensitivity and specific selectivity, in water and in human blood plasma.
ISSN:	0003-2700 1520-6882
DOI:	10.1021/ac504037v