Activation of the Si–B Interelement Bond: Mechanism, Catalysis, and Synthesis

Interelement compounds--compounds containing an interelement bond--are attractive main group element precursors as these provide the opportunity to transfer both bonding partners to an unsaturated substrate. All six possible combinations of these three elements are known. Out of these, the Si-B bond...

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Veröffentlicht in:Chemical reviews 2013-01, Vol.113 (1), p.402-441
Hauptverfasser: Oestreich, Martin, Hartmann, Eduard, Mewald, Marius
Format: Artikel
Sprache:eng
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Zusammenfassung:Interelement compounds--compounds containing an interelement bond--are attractive main group element precursors as these provide the opportunity to transfer both bonding partners to an unsaturated substrate. All six possible combinations of these three elements are known. Out of these, the Si-B bond displays several attractive features.
ISSN:0009-2665
1520-6890
DOI:10.1021/cr3003517