Open-Flask Synthesis of Amine–Boranes via Tandem Amine–Ammonium Salt Equilibration–Metathesis

Open-Flask Synthesis of Amine–Boranes via Tandem Amine–Ammonium Salt Equilibration–Metathesis

An amine–ammonium salt equilibration–metathesis sequence provides high-purity amine–boranes in excellent yields from sodium borohydride in refluxing reagent-grade tetrahydrofuran in an open flask.

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Veröffentlicht in:Inorganic chemistry 2015-06, Vol.54 (12), p.5618-5620
Hauptverfasser: Ramachandran, P. Veeraraghavan, Kulkarni, Ameya S
Format: Artikel
Sprache:eng
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Zusammenfassung:An amine–ammonium salt equilibration–metathesis sequence provides high-purity amine–boranes in excellent yields from sodium borohydride in refluxing reagent-grade tetrahydrofuran in an open flask.
ISSN:0020-1669
1520-510X
DOI:10.1021/acs.inorgchem.5b00572